Quiz_4_Key_Summer_2011

Quiz_4_Key_Summer_2011 - (g _. NAME \ ““C Y ID___—...

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Unformatted text preview: (g _. NAME \ ““C Y ID___— Chem 308. Summer 2011 Quiz4 Section C1 1. (2 pts.) Give the reagents and conditions needed for the synthetic transformation below. 0 0H "’ o?“ - I 'u I? _ ' \ L. {hi-R417 't I I QBCL‘ {l . F C ' (fig->1 “T J H to; ,3 lam ) 2- (2 935-) Give the major organic product of the reaction shown below. \ r-J/ O H l N catalytic H2504.{- H20] '\ 0* 0 ? o c/ 3. {3 pts.} Write a detailed mechanism for the equilibrium reaction below (proceeding from left to right). Use curved arrows to describe all electron movements. and indicate all formal charges clearly. 59 I H Ht.— 0' at o OH catalytic HCI. H20 H0 H ’\\r ll CD (ml) j H n L "9‘ H .. \g‘ A \. f , :. H's . a ‘ 33$ .{OHH NAME E: y ID Chem 308, Summer 2011 Quiz 4 Section {22 _L (2 pts.) Give the reagents and conditions needed tor the synthetic transformation below. More than one reaction is required. Number the reaction conditions separately, as usual. H ‘ Hue} H o fickngiNQ‘E’F3 ‘3) AA M N/CHa H (Hi-11) OH I CH3 H E) , _ 9% i. HucrrquHH-(txm z. unit—Le (m— VH'L-‘fl. waste.) USHER 2. {2 pts.) Give the major organic product of the reaction shown below. 0 HENNH2_ KOH, H20. A /_\ ? l J 3. {3 pts.) Write a detailed mechanism tor the equilibrium reaction below (proceeding irom left to right). Use curved - -P%/ a“? O 9.“ *- U‘A catalytic HCI. CHSOH 0 OCHa ‘r‘ ——-——-- + H20 1* CH30H ‘— ii i "V c“ . 9“ Ci} 5 H H u o'- I \ ED ® '- b “' “M '3 Q g ...
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Quiz_4_Key_Summer_2011 - (g _. NAME \ ““C Y ID___—...

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