Organic Chemistry Lab Solutions 65

Organic Chemistry Lab Solutions 65 - 5 Br[Ph 3 P-N=PPh 3...

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75 O O N 2 O O O C O HC CH 650 C - N 2 major minor CH 2 =C=C=O + CO 2 O=C=C=C=O + CH 2 =O CO + Chapman, O.L.; Miller, M.D.; Pitzenberger, S.M. J. Am. Chem. Soc. 1987 , 109 , 6867 Br COOH R 1 R 2 C R 1 R 2 C O Br COCl R 1 R 2 C R 1 R 2 C O C R 1 R 2 C O O O R 1 R 2 R 2 R 1 R 1 = Me, Ph, H; R 2 = Me, Ph, Me 2 + Mn(CO) 5 Br + [Ph 3 P-N=PPh 3 ] + Cl - + Mn(CO)
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Unformatted text preview: 5 Br + [Ph 3 P-N=PPh 3 ] + Cl-1. SOCl 2 2. [Ph 3 P-N=PPh 3 ] + [Mn(CO) 5 ]-[Ph 3 P-N=PPh 3 ] + [Mn(CO) 5 ]-Masters, A.P.; Sorensen, T.S.; Tran, P.M. Can. J. Chem. 1987 , 65 , 1499...
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