Organic Chemistry Lab Solutions 160 - 170 O R h O NH N tBu...

170
O
NH O
O
tBu
R
R
N
OtBu
.
h ν
Danen, W.C.; West, C.T. J. Am. Chem. Soc. 1971 , 93 , 5582
R
NH
OtBu R
N
OtBu
tBu-O-O-tBu 2 tBu-O
.
+ tBuO
.
tBuOH +
.
R
NH
OtBu R
N
OtBu
.
CH
4
+
.
+ CH
3
.
N
2
+ 2 CH
3
CH
3
-N=N-CH
3
Danen, W.C.; West, C.T.; Kensler, T.T. J. Am. Chem. Soc.