Organic Chemistry Lab Solutions 205

Organic Chemistry - 215 Ar-S-S-Ar HO Ar-S(O)Cl Ar-S H2 O h Ar Ar-SH HO OH Ar-S=O S SAr H2 O2 Cl Ar-S=O H ArS HO Ar-S-OH Ar-S=O Gilbert B.C Kirk C.M

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215 Ar S OH SAr . + Cl . Ar-S=O h ν Ar-S(O)Cl . . . Ar-S=O . HO Ar-S-OH H 2 O 2 Ar-S - H 2 O Ar-SH + HO . . . Ar-S=O - H + - ArS - Ar-S-S-Ar + HO Gilbert, B.C.; Kirk, C.M.; Norman, R.O.C.; Laue, H.A.H. J. Chem. Soc. Perkin Trans. 2 1977 , 497 . . . R-S=O + other products R-S-O-O R-S + O 2 NH 2 COOH HS NH 2 COOH O NH O NH COOH
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This note was uploaded on 01/16/2012 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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