Organic Chemistry Lab Solutions 271

Organic Chemistry Lab Solutions 271 - 281 hν N tBu tBu _...

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Unformatted text preview: 281 hν N tBu tBu _ tBu - N2 Cl N : N N+ Cl Cl Jackson, J.E.; Soundarajan, N.; Platz, M.S.; Liu, M.T.H. J. Am. Chem. Soc. 1988, 110, 5595 R1 N N : hν _ S+ R2 R1 -S-R2 - N2 Ph N H hν - N2 : N Ph R1 -S-R2 Ph R1 _ S+ H H R2 Romashin, Y.N.; Liu, M.T.H.; Hill, B.T.; Platz, M.S. Tetrahedron Lett. 2003, 44, 6519 Ynols (hydroxyacetylenes) R OH Reviews: Kresge, A.J. Acc. Chem. Res. 1990, 23, 43 Staudinger, H.; Klever, H.W. Chem. Ber. 1908, 41, 594 (confirmation that ketene structure is not that of hydroxyacetylene) R OH RCH C O Meinert, R.N.; Hurd, C.D. J. Am. Chem. Soc. 1930, 52, 4540 (coining of names "ynol" and "keteno-ynol" isomerism akin to keto-enol isomerism) ...
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