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Organic Chemistry Lab Solutions 273

Organic Chemistry Lab Solutions 273 - 283 Index Acylium...

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283 Index Acylium ions (oxocarbonium ions) ........................................................................................... 1 N-Acylonium ions (acylammonium ions) .................................................................................... 2 Alleneoxide ...................................................................................................................... 2 Aromatic pi-complexes ......................................................................................................... 3 Charge transfer complexes ............................................................................................ 4 Sandwich complexes (metallocenes) ................................................................................. 7 Aromatic sigma complexes (see Meisenheimer-Jackson, Janovsky, Wheland) ......................................... 8 Arylium ions (see phenyl cation) .............................................................................................. 10 Aziridinium ions ................................................................................................................. 10 Benzyne (arynes) ................................................................................................................ 11 Betaines (phosphonium betaines) ............................................................................................. 18 Biradicals ......................................................................................................................... 18 Thiele hydrocarbon ..................................................................................................... 19 Chichibabin hydrocarbon ............................................................................................. 19 Schlenk-Brauns hydrocarbon ........................................................................................ 20 Müller hydrocarbon ................................................................................................... 21 Norrish Type I ......................................................................................................... 23 Norrish Type II ........................................................................................................ 23 Bridged carbocations (see halonium, non-classical, phenonium) ......................................................... 25 Carbanions .......................................................................................................................
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