Exam 3 SP_08 - Chem 112 Exam 3 SP 2008 Name _ Multiple...

Chem 112 Exam 3 SP 2008 Name _______________________
Multiple choice. 6 points each. Partial credit may be awarded if some work or comments are shown.
Assume 25 o C, aqueous solutions and K
w
= 1.00 x 10 −14 unless otherwise stated.
1. Hydrofluoric acid, HF, is a weak acid with K
a
= 6.8 x 10
−4
. Calculate the pH of a 0.200 M solution of
HF.
a) 0.70 b) 1.17 c) 1.93 d) 3.17 e) 7.00
2. At a temperature where K
w
is 1.4 x 10
−13
, a solution has a pH of 7.00. What is true of this solution?
(circle all that apply)
C.
3. A 0.00100 M solution of lactic acid is prepared in ultrapure water. From high precision conductivity
measurements, the acid is found to be 30.90 % ionized. What is the K
a
for lactic acid?
4. A buffer is to be prepared using acetic acid and sodium acetate to a target pH = 5.10. What ratio of the
conjugate−base to conjugate−acid must be used to achieve this pH? K
a
for acetic acid is 1.75 x 10 −5 .
9.80
5. At equilibrium in a reaction, which of the following statements must be true?
a) the rate of the forward reaction has reached a maximum
b) no reaction is occurring
c) the rate constants of the forward and reverse reactions must be equal
d) there are more products than reactants
e) there is no net change in the amount of any reactant or product

6. K
b
for a certain weak organic base is 5.72 x 10
-
6 . What is K
a
for its conjugate acid at a temperature
where K
w
= 5.01 x 10
-
13 ?
7
7. Which of the following represents an acid and its conjugate base (conjugate acid/base pair)?
-
2
8. The following reaction has K
eq
= 4.91 x 10
3
for the temperature at which it is occurring, in a 1.00 L
vessel. From the instantaneous concentrations shown, predict what will be observed over time.
2 Al (s) + 6 OH− (aq) ↔ 2 AlO
3
3− (aq) + 3 H
Instantaneous amounts: 0.050 mol 0.0112 mol 5.49x10 −3 mol 0.0125 mol
2
(g)