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310MHWSet8Fl11Ans - Homework Problem Set 8 Iverson...

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Homework Problem Set 8 Iverson CH310M/318M Due Wednesday Nov. 16 1 Chemistry 310M Dr. Brent Iverson 8th Homework November 9, 2011 NAME (Print): _____________________________ SIGNATURE: _____________________________ Please print the first three letters of your last name in the three boxes
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Homework Problem Set 8 Iverson CH310M/318M Due Wednesday Nov. 16 2 Score: _________
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Homework Problem Set 8 Iverson CH310M/318M Due Wednesday Nov. 16 3 Br Br Br Br Br 2 Br Br Br 2 H CH 3 H O O NaN 3 NaSH Br N 3 CH 3 C C CH 3 SH NaOCH 2 CH 3 O 2. (3 or 5 pts each) For the following, fill in the boxes with the product or products that are appropriate. You must indicate stereochemistry with wedges and dashes. If a racemic mixture is created, you must write "racemic" under the structures. h ν K OtBu 1) 3 NaNH 2 2) H 2 O H 2 O, HgSO 4 H 2 SO 4 1) NaNH 2 2) 1) (sia) 2 BH 2) H 2 O 2 / HO racemic HBr ROOR / h ν
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Homework Problem Set 8 Iverson CH310M/318M Due Wednesday Nov. 16 4 Br NaN 3 PBr 3 OH N 3 MeSO 2 Cl H 2 CrO 4 O H 2 SO 4 OSO 2 CH 3 OH NaN 3 N 3 H 2 CrO 4 PCC H 2 O OH O OH OH OH OH H O 1) OsO 4 2) NaSO 3 H racemic syn addition Fill in the boxes with the structures that complete the reactions. Use wedges and dashes to indicate stereochemistry when appropriate.
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