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C566lecture25_000

C566lecture25_000 - C566 Master Lecture Notes Lecture 25...

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1 C566 Master Lecture Notes Lecture 25 REMINDERS: Midterm 2 will be on 19 April, 2011 during class CCJ traveling 17-19 April, so no office hour on 18 April Don’t forget- final paper due during finals week (noon on Tuesday, 3 May). Forbidden Transitions- observed via (2) Breakdown of the Born-Oppenheimer approximation BO: = el ( q i ; Q K,0 ) vib ( Q i ) Relax Q 0 : el = el ( q i , Q K ) Example again: BENZENE Ground State Excited states frp, * S 0 (S 1 , S 2 ?) (S 0 ) = A 1g (S ? ) = e 1g e 2u = B 1u + B 2u + E 1u (S 1 , S 3 , S 4 ) (S 2 ) = e 1g b 2g = E 2g (x) = E 1u (y) = E 1u (z) = A 2u b 2g e 1g e 2u a 2u
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