exercise 7 - Chemistry 312 Names: Exercise 7: Energies,...

Info iconThis preview shows pages 1–2. Sign up to view the full content.

View Full Document Right Arrow Icon
Chemistry 312 Names: Exercise 7: Energies, wavelengths and colors of metal-ligand complexes 1. a. Given the energy information in the table below, calculate the ligand field splitting energy (in cm –1 ) for the complexes shown. Show your work. P is the pairing energy. Complex 10 Dq (cm –1 ) P (cm –1 ) LFSE (cm –1 ) [Re(H 2 O) 6 ] 3+ 33,000 15,000 [Mn(H 2 O) 6 ] 3+ 21,000 25,000 b. What color would these complexes be?
Background image of page 1

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
2. Classify the d 3 configuration into its L and S microstates. Below is the beginning of the table for classifying those microstates (analogous to Table 20.6 on page 490). M L M S = –3/2 M S = –1/2 M S = +1/2 M S = +3/2 +5 (2 + , 2 , 1 ) (2 + , 2 , 1 + ) +4 (2 , 1 , 1 + ) (2 + , 1
Background image of page 2
This is the end of the preview. Sign up to access the rest of the document.

This note was uploaded on 01/19/2012 for the course CHEM 312 taught by Professor Staff during the Summer '08 term at University of Washington.

Page1 / 2

exercise 7 - Chemistry 312 Names: Exercise 7: Energies,...

This preview shows document pages 1 - 2. Sign up to view the full document.

View Full Document Right Arrow Icon
Ask a homework question - tutors are online