Lecture Notes 1 - C/Mpo 7 [bonds are sharedelecbvnsl...

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Unformatted text preview: C/Mpo 7 [bonds are sharedelecbvnsl Va’emj Mud ’Dr‘A-wlffi chm/band 'H and X (halvzn) maké one, banal O and S «AA-he, +1.00 banJS 605E sul-fuk can matu— More. N and 'P MA-ku. Hwee. boncls bud" ? Cm ‘MA-‘u- more, _ C «MA Si. «Ada—L {bur boncl: I? I CHqO = l-l—C—O“ H I V H whack About OH , 0H2 , OHS a,” gist G) .. .. ..+ ' :9-—H :C’D-H H—O‘-H H H also . Q UHq 1 era charges Basis 15TskeH holds 22. H' 0' H71? wisheu holds 8e. sand 1’ \M-ve. 345ml (cl-orbs) H g! H +, u‘ : -- I - I \xecASAQ—H u-(;_._$——c|:.—“ \ -' H H H “ {OFMG‘ club. rat .5 Whai Abou‘t' Carbon, (526 F16) C 1 2 2 7- z 1- = ' o . , . . 5» F .C .CHL dosed she” lrehfl bridbh {16m H H ,H .‘ . ._ H.“ ’ H \H 2' H Qurvmlen“: I cum who ‘4 Galactic]: orbt’caLs cud 21.0mm Usinj sF3-Bbrid orb: g O p In 0- ?florb suorb . Sf‘wbrgd (saw/Le offhur 15 cMA/9-2 ) 'kdmvdent C ‘tS "t‘efihhedrato . ° «Fur a“ bond angles boron mm: 3 bmds «B. =1.» is. + Fag—E: Lew‘us SMLhres bonds = \Unes (shared a Ipair‘s) 3 = ekecbrons not shared H surrounAacl. (3) 2e. 2nd far-(ad elamewEs b) 8" [5+6 b—t—cd deck-mas Halt = *F I 3 ‘f .5 6 '7 H B C N O F Hzco \2 ua|enca e—‘ed-ron if and“ hand-rd \Cwo accoufi'ks For 6&- frokbafly in socél'an/ I—3A More MAM/ole: of szl's Sbuc'ltures i/Qexdnance, MRI-via £7.ch _ ” +l/5: ” +;o.,‘- H~Q—N\ 4—» [4-4 -—A/\ "0": —- .o \9: +N/,9 J" “' H—o- *. \‘ . o ’ 2. H \ also “fl/C— can rthKe. H0"~ H /O. _./L + r J K «3 \'o _,/L hlhawet-hane, .“(AM—e. L5 9.2-0 3 TAbLe. [Jo 27"23 veg iwforkant‘ n‘rhv methanz 2. uh). rcsommnce. S'E‘rud-flf-es bud: mthj\ ni-K—rlte. .. f’; "j H u .- (143“ng =Q. <—-? CHsfiogNr—p’. I ’I " wu nor Cowb‘bu‘bar oiruadx arrows Show szcMw‘om'r movemnfs Consider . [’6’ .l \ ’IO: 4—1»- \< C, I I pf" ’ \9 ’H ‘. ’05. .- ms' \ IO: \ / ' ..c.—-~c’ «—--r -—-c:-— C§ ’ To? - ’ o’- I’Bomlin. (6" Shark 7 \ J j OUJCV z V1 2T2 L‘ 7/ fa «'r-I'nj 5? (In s > A (see. aJs‘o sec 2.2—2.4 ,2.6) H~H + Hum/mote. = 2 H. H33ka is +h¢ boncl emu-3L3 cf an H-H bone! ( |0Ll kCaL ) shcnj'tk no A ‘ W" “"914; .. E ’t bod ‘ ‘4 'H dissocid'h'n \ "/ H J C—C\ d‘d: e. " - I cum ll H/ I H H H 1.543% 549'“) c—c Mud aqekxflwL H egf° H \Czc/ygzo“ c=c (399.4 sharia?“ GHUWOI H’” i‘H 2H. 1.33% ' mfg en < 376 x Z. e‘HAena \s na't as “s—bable'fl I V—orb O ‘20. <—-—- 3 SP7" Mbr'135 a": ’ / / 0c 09 SV’C. H —- C EC“H \{Mar 1.1K bowl \enqtk “~— .- -a—au—‘n—u—u ~..——.—- «two orkkojond Q-arb . 'hoa Macaw .5? bond inj own-Ms Ionic anal ?o\ar Co-uqlewh (Bonch'j’ .I‘S Na“. bk in soh'c‘ 54H,- . n ‘ H ‘ vac hackkex b (tame, bonds areVH’r \OWJS) ’K' Couowtbic afwa-cLo‘a not H ___(';"L e“ sharirj u ‘ . ' 3+ .. 3- 8+ .. S- H : H...’ 9} : L.—— folar cavalen’: 60nd non—ink" coucdevr‘: bond ~ '{cndencj 03C A‘EOM +0 (“VASE a“ :- a\ec‘~rohfii\+‘wn«( a. rid."an S‘h’h-Néc. “ML—’— kerne‘ .H (Marat 2.\ E SSE-5'6 Bond dipole: and Molecular dire/e mowenZL: ' sechén: 1.5,1.10_. ' {life/e moment ju : (change. dc'f) x dlki‘anca. 5* $— . . 75/ X - Y (have. difference- fro/oar £70 ma! {2 cleCl'ranLejA l'NI'ly diffinwce, H-F, H*Cl eéc hA-Ué bowel cli/Mle: and, .sfnc& {14.2. aux. alS‘o «molecules, M3 hMe/ mole cwlar dipole. Moment“; . 2.5 Ll C—H ma C~C. are non-Polar- bond: Molecule: -H1a.‘l' 1144212. wolzudar 49/9012: ova—called Polar; ane’: that lack «o’f/oclz, are. Mam—Falar, Newpolar— molecule: can. Sb’ll haw/e. [DO/(2P bonds H H '-"- C = dual: ll'vLmr-gaam¢+r7 banal dipole: cal/me l . also can be M: fir fan: . C03"Z) NH‘I“ are «PAPA-Mle: . 1 felmhedral Planar- H +'—7 \CF—O: has a. MolecuCaralifde-v H so does CHLCIL buck nak‘ _ Cqu 1'56 Adda-j UM” W2“) V Br/nfl—cd '. Aafuhes an Add a; 4. fN'tO“ d°nor a base is a. Pro-Eon acur‘br . , done. Lawn: : base 35 an electron 913!" P acid I: an elccflvon Pao'r' Accéfbr (flu. H"' is one.) no++luonlj , Luci: acid) + _. "'9’ + “"F -->‘__. H—q—H + .F H H B'fsns‘k‘d use add Con}. acid can' . base Of 0 H F —~—-‘—-———_-————_-—.-— u'n {this nae-Hon Hm. side, wH’k H3O+md F- is M4: fA—vored , aid-«Lat 491.”. conS'Ean‘t is \0'335 fir HF K‘s ‘0-3353 RF is an-‘j S‘ijh‘l‘h‘ 3on3“! wha? ‘ H3o+ is ashlronéar add “Hahn H~F .- c'?!’ is ¢L s-l-mrger (more reach‘ve)(mu than H20: An ailJi-l-u‘ scale. (sea (Able/LB) 2:“,0‘3 am > HONOz 9.: I430") HF ) cuaazH ) go" ) NH, PK» 4? -I.5 3.45 we ~I5.e 35 K 1-7 p a is used a: measure of Br/nsfeal acid S‘éflnj‘f/t P’Q.‘"0 K‘s H-I-law 1“ ’9 jl'A'J . O . u conseder ace-he and CHBCazH H—‘c—c” zl-l Pg: \l’ . k ‘3' to“ vmeaAr' wean/awe 0&3th . . . . thanCCG“ “’“on M’cenk a} tough-hon defends an 1>H Lib [x] (cu3ca{] H = K _ P P a + [03 [HA] ’ 4'15 + to} [cuscozfll at S ’5 EC“3C0£H 1 at- ?H 3.75 (more acidfc) , [cu5q1/[cuscozu3 = 0,1 90 . in flu, form of flu dad. H~F less acidq'c than. H'Cl tau! thoujk f '.s and! FW4 *7 \ess A'Q'rkc in «for H" out“ 15‘skcfi ‘ also show bone“ a - r... / ._ F;\) H’C} ———-—-" F—H + =C,l' 't A K = I0 ’0 . T shun] base. 1 : weaker base s'l-vro ck waiter ' ‘ ,I..8 afier Acid [Base 7559th 141% ' - ' ‘ ' ‘ - g ___ Leglisn. ecu/S 1.04:3? fijwe H+ (‘ ’{30 tr) in wafer base: Affin/ 0H- No'l‘ very useful £5001; L513). (once/{— wild/e! Aff/I‘CAb/c I}: again/c Chet/"I157 ‘ "Acia’= eI'lnair arcs/for, Bare = e'laairdonqr- Addacf‘ = combinofrén ofa. acia’am/ 643.: Ci") (‘il fill} a I ', O .- 6"; '3' Ar“ ---7 agilfwm—cc 1 .6343 6L CH3 6" hue acid addud: : + H .r -——-—-'r ’ é} '" H ' H-Cl -: N07 a tuna: acid ‘ ! ' “-35.: ———~ In. :9}: l I '4 H ' Lewis "alduc‘l- " ‘444ud- " wcahtr I base Luci; 5J3!" I .——'c——-—-——-—._ .u—I—n— nun—“.— u—-—-———_— Ammonia, auum'LA, wad-er (on‘evh‘ns Mrwflda Ian: “5qu $0»; awuom'aL ackinj as a Lead: base. are ‘Hnere, anj Lewis acid +szis bAse. gens? 17-36 \fes’ one wPlafns C02 1- HZ’O gives an aétdci SMN. O (s) a: Z .— .- ’l u; ‘ c,- H0 i —_' .H'g—CE'OZ- + H20 (—- . + has; ant—I3 adducl' hucleofkile eiec'krofhi My \kber 3003 H See—l "‘chleo‘olnul'c " subs-H-hfia‘an; H “ n +7 \ .. I. / .. - ,_ —CH :CL- H't‘dt’ C‘Ct. a Ht? 3 f " | I 5 -- ' H H H anoHuzr 14me of H330: act-in} as A Lewis [use—r ' . Kelfif-fu‘e Ada/it’- anc/ Bastbiz!’ - - (40a) 44! 6/! 07‘ 7745/6 1.71/0jaa need, ZLU éflaal?) no? Hurt" much series on 1—6 esren‘h'al Ibetter'éa know ‘Huz 7990191912: that" influence acid/"15] t'hué apt/mar 151 sec, 1.16” ‘ c1302” > Clgcazl-I > 650-509! ,) ClgcléaI/zflza mid- A ‘f ,5 acid“; ‘ 1 [caJACI‘CI/C : baa/z :a. J 190(er ‘ ‘ Hinducfi-ue efficf u resonance :‘hduc-HI/e shéilijd 92‘9"? my. base, bo nd sirenji'fi H—Br > H-cz > H-F adt/T‘élb'nal Lewis 4/; wry/ea" “’2 “mm; H @ i HNI + fl {’0 - 3 -- —————3 HN—C—O Mr 3 I ' L bite, Lanai H adJuC‘t a P CO ,_ WWI)" B": “9 H3” + {5" 14.3 MWCIL adduch "re/mid ” bAJe — ' 7w 6/ £6 ' W‘W e Iva/r firuac n i iIL'7 e I’M/Hes I \ re/AfiVe [ball/62%- _ chaij diSfZFJaZ/h’laffer: " @6. A): I -Q -— %% S " C —CH ’0: _ a." «- E “3 2 .. 1 “’5 ,(&C_CH2‘Q:O Fl! 3. 622 sec, Ia/‘L/ 5‘! [/6 Q H—A 4 139 :5 A + H'B my iii?” eon5io’er M” baJeJ -- @brfdgrl'rén mufflers — H .- I - o a z : H~N= >> Hfiyr > > 0136—” ,1; H NH (~36) NH; (9.3.), @3451), CH3CENH («2), C°"S£‘.h‘fi°'““( 150W“? mu! SMGW' shar‘i‘harzcl I‘m Satan/c s (.7 —- 1.3 CH3N0Z and CHSONO as [Friar wmfte a} isomer: anoHner resonance {lama “ .. , , .. -9-—N:Q; 4—7 CH3fig-N—‘9: CH . 3 + nof: ns‘jooc‘ . - - . _ Md: act-eh wNSlder‘ IMQ‘HAJ m-En‘C and. MC'E‘U‘ isonH'nk ' 4 H H'jC—CflN H:C—-N—'C ’ / H H (CH3)ZCH0H and CHSCHZCHZOH are isomer; >0“ and No” (n Shari-hand shorthané‘ assumesv kfldrijzn a": any C wH—‘aou': Ll 'bonc‘s’ I 5;” e: a Molecules, MEN (3.“ Lia) m slm~1>es a? mask comFouMJs can be, ?re&?¢£cd \pj Assumin ‘H/LL bonds and (one. Pains art “file—Ewe. MA rage“ each o'HAer bonés are less revulslve, l4\ ,H was/c ’0 H 120° fi‘ 4 41“”. f/C: :: ‘ \ ,,vH Q‘anar "' CHB @1043 ’Et'kk kedraL ...
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Lecture Notes 1 - C/Mpo 7 [bonds are sharedelecbvnsl...

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