Lecture Notes 3 - \ShA/aésaf Molecule:,(deficlzhj 31D) and

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Unformatted text preview: \ShA/aésaf Molecule:,(deficlzhj 31D) and ‘ConfirmA-l-wn: ‘ . ‘. H. re’mem her 7< H _J\‘;H . . A' H ‘ . " n ' H’k , Whhedral . u , n ' ' . - “nit”, s—Lnjjcreol 0.9mm? Newman ?ro:‘¢cHan ,(Uiew down. 'g'borto‘) ‘69” Wk" H H ra‘l-A‘Hon flan occur do 3,4/ ethanez 4604f C~C. ad'oy‘e ' bonds H “N ’7" n “ H' . Sflfiwed ' VIE. CH3 " - H .0, “ ‘..V H ... . ‘ - C", an“ t - gauche comes Maia @ 3.316“! aéaue an'h' knot fha'f differeni‘ Man 2,7gefiane) (but Cfg/CCI} eclifse is >6écal) '21 w) m“ . C“)/ I CH3 I . % v a as" H .H a eth’ set. I 5, s r ed .- r 5&0”sz :3 "GER" I am! enerjc.‘ dffifarencc, 0.8 kcal/mol. 80. +1) 3.5 and then ‘P. I22 40:, 3.]? A6 = —RT£KI< what does +1441“ {MIN}? a6ouf {m czai/ibnizm popula‘h’dns of gauche. and anti—bah g/ ’ whai’ » Aloan .si'Ajjerec/ w eafiéseJezLéane. » mew]! EMU-cps dou'fsfr'm, Htejjum]: éefiueen .S‘é‘tljagrcd ConformA-(zéw, 2.: CC, #2” ) me; C}, Haw-L fat-icin-‘oPane. ' H‘ A " I! see . ' _ H sec. 3.5 H a. full. 360°.rai-A'lfln About C~C In (yo/t}; eel/Lang: i: not fasfl'é/‘vfl J t D:- 4% leg 5, fifiw’oujcr: (sea 3‘11) ciJ/J-ran: homer: .3 .5 ‘Et — .. Y CM} CM ‘lxans ' . " V a _ u, x"- .moi Infanconveréib/e, 5 fl- . ‘ - . . , inhrvronflcd-ii I: game-fr“ “Omar: "canfimd‘l‘léual'" iJomer: . H / H u‘F “(W HQ”); 4 H almwa ii- | Show‘mc! 3 K}. / ' UL? PoanénS L an easifi-fén / +0 dmwi. / . . \ H ‘ . HM" ‘27 shows jaudae bubcmc. t' H mLaA—che'rns (v 0.3 each dogs-EA “(53 a? 4—— hqW——QMA\'Y.S’ bod-S,€'EQ not: 9oFU-EAEQJ Consider- d; Md brqu l,3-d:fiet§j‘ Cjclo We. CH3 . m g ’ bad-h Mal "M5 ' Cu} 9; both e um ‘5 me shun. Me— > flovwfié . w «ac Me» Runs Shah; h {—3 CS “[0 V m > >> c4 H8 > c3146 Cal-ha CYHNF “"4 C'IOHZO MA. 10M- r . a; L’- £3“ wk; no 54mm Mn'nor .10.... ' no 2d: 5'. I V («finch ‘ . P 3 5(7er 4M3 no rchefa. Sam «hips. _ «1" “ M‘McJ 53* cf . PS “1 - do: Wes-dam ~crunfi flu. r /# Source: of r1117 51574121 “HPSQJ . H ~ _ angle SHAM echpsivj ‘ t can‘{’ be hvoldLA l'n Ljdo?ro?W fiE—é re Cat/l heat cam W76}: (ea/Vt lpro 212% re/A Aye > $95f/f'll’éf M‘ZeuL {Mg/“1) éfm C4 H8 /42 .7 £63 CS Hm I S 7, 3' _ a 5 . 5;sz . [56.0 CMst 55,0 , * (CW/>1" Mm:— /5é, 4 /r QAmg—Isek, % m Zecvéotz /M/< 2;” 1‘4 7PM, if“: 3'7 /0? ...
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Lecture Notes 3 - \ShA/aésaf Molecule:,(deficlzhj 31D) and

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