Lecture Notes 4 - Choir. '4 312,1. «nut 4dlow atukb fin...

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Unformatted text preview: Choir. '4 312,1. «nut 4dlow atukb fin 4:.o4t‘ durs‘uj led‘hure. kg ?ofnts 1) m’cekconversl'ori'auas “I of ,. alcok6\5 Md “(8‘ %L\L“Qe_: | moH RCL ear,—:,¢&4 z)‘ KOH +H>< : RX +Hao mszQMiSHc. definil‘s {MFaf'Equ't‘ '-{.l 418 LUZ.) 4‘ T 4. N, 6416/ 4,10 PMS PASS 3) mac—Hon \‘n‘Earwmdtqi‘es _ + \ carbocAbx‘ons \$/ am! radicals ,C' ‘ I q) \oand awed“ij ruse, "n'vrzéchnj mcfiui+j 5) mawdnj a\coho\.s Func’o'ami Groups (Hm. sources of- reac‘h‘uflj) ‘ Mo$+ «sou/tic Chaut‘sij MQCE‘OV‘S TnUolu‘e; vfwwckowd (slow-‘35 ‘ nc‘fi' m “abocavbm - sm‘cbn . ' §H3 CT3 arse. kcep‘hcn CH3 ~C-H ~t Brz- ——-'v CH3-c—Br + HBr ’ I 1‘ ca} I ) cog MorLszat QJ I "if—9,10 Wald: W Mark needecl ’(Ablb 4A aivcs “5“ 5? g'KAVLCA'tO'qul 3(0ng {5r now cu. and +0 know: Q‘COI'aols'. thdeS, ether, a\de\abdz ounc‘ carboxghc .actd . \ ‘. . 1313-2. w» douh\e.. MA Nqfle. bancis’ h ques 5“ g altar/ya: our: aka funch‘anqk j‘mufs, [\Cr-O («News HM— Clqr'bof52( Exam? ~COZH 1‘ arbaX3(lc act WWI) \ -IC—OH u an alcohol or Bdrog‘ 640m? 0 u _._./\/\<:’°“ ‘ w H “o PGEZ (a Quad-30nd Sech‘ons $2., 4.3 Mamf'na «(5.131 hedge: mi qlgohoLS» Comm-on ML: Sbjkmfi'H‘CaA‘MO-Mcs (mbs+\+u+ive.) some Common. mamcs qr?— worH/t CHSCHLI (bk-ail “whale—y Cu3x _ ‘ I Br. L50?VO?3\ MTOVD“ fi...’ CH3 LcH333C O‘H kart ' bu‘EQnGL cf -\:,- bu'Ej‘ alcaho L 'twnfar-t-qu‘t \=° ‘Mdud; ‘HLL ¥unCh'0VLO.L _<‘1ou.€s on HAL erm'n chain. 'eHZOH 3 CH CH ~CH~CH (H at ‘4 3a 2. 7' 7' 3 3*chloro fZ-frof‘gb“ ‘ butangl‘ \C—OH \ ' "" 7 ;C—X _(__‘3 (\45525 SE atcohols AM& hahkle: CCHs-X] Carton A‘E‘oms aH-qcku} funcbfa'mal giant; .QT§W6VLJ . SQCOILAQY’ ‘ dekrvM'meA HAL 1* +0 m ea rinj mkj 15H: (Near-bank 7 carbon class defirwuha. rear. ‘uf‘Lj and NexHAocl ai— STA-FMs-is . :Pfaterfiés (Fungi! bind-x! 4+ adcowfls Md O.\kj\ ha“ das sech'ons 4.5 MA 4.6 9&- auevx ‘Hnoujk R-CL as PMqu (basgd ‘M égrola Womafl'b) as K-OH [AffiCAe—r" boiltkS fo'lu‘es, are ‘l-afifiml" H—banJMLS I , alcokoIs ha-u-g much 6 S'IK R/ \:,+...<3 \ 4 IL I Qavhkd 00-14 “look/$694!; :«kmc‘néw Moi-“a no bandska “fluoroalkanzs qrz, wejké'. bo‘d \auer Wm .50“ «Hz/tugs fpz-“SK‘L‘S Ch H2M4 1-x \ass dense. L-F-loa'l‘. on) wood” mm x: at) F, OH More. dense. X; Br‘ I ’ bud: (Hafiz- MA CHCI} more dams-z... wage“ somb: l; +1 ‘- 4“ BArocarbonS MA hqlocarbons are. insokuth—z. CHsoH, CH3CH20H’ (CH3)2_CH0H and CCH3)I3CGH are. soluble,~ flaxle Misdbla/ FINALLY CHEMISTRY works, wings-bar awul beHer mo ) I? > I: 4!: . wing? ? Wen/Va Amics CrelA-‘h‘ue SHbiliht’es ) M about fine. 5 L, \MULS‘L b!— a. mahu§s¥1'c‘g¢ahre. 'HAK (Lack-(3w fisroceeés \‘n ssz ~ for is a\co\l\o\s ‘H/ULSKPS are. Q ..... t) ' R—OH + HX .272 R—on “Mes: A VAP‘A ebujhbt‘uwk 2) R‘OHZGP ~——v R+ + H20 a flow bonA breakalvjl(¢lis:ocia‘ln.on) Slap 3) 11+ + nil-7 —--—-v R~CL bond 3&3 R-Ol-‘L+ GM :1 'R’+ are C («Med "xmkerCa’cea-n \ec’cure makes 4 .' ’ _L\_/—5 Reachém Course “Eco? cums \VI'ECY'MLG‘I.¢Lb€S l braus;'&1$u 555:: com h'nh. reactants «44.4 Products I‘s mat ‘Ts'; a-Lso («we C(tQAA-CECV‘I‘S'LI‘C anew-Wis 1'5 x 1“ I , \ E Teadrautlj I" K I ‘ "-'_ ’ ““'" - \ ‘ \ ~ Eraduct Veadflim raovJ'firME: -----" VePrZ‘ZK'ES 4. $\A(j‘€/ SEQ? 3W, $u+ no‘t 'E‘hosax'm ckkarq' W one. Manete.’ H HI (m, -= “0...!wa . _ H '9“ WWW: Jr 3; a binder—why reach’m HA: {1) (3-503 Préa‘ucbb“ g; k EOH‘3ICH311 _ fly/'6 'ChA/a. 4 Mia: cont'cl. (CH3)3COH '+_ HCL ~—~v (045336161. 1- H20 mechaazsm, Skown. as a. readiovt course. ewefix‘ diaflgxawv—a Szc. ‘+%-9 fig. 9M1 1’52. I = ‘m'lzrmeoL. A (CH3)3C.+ (7%c same mfgrmgézkfa also 79/1445 "'1 E58 Wk) Ac gxoufs 541410? Use, carbocxtbésns 4.. + . H / H vs c .. ‘ \“. recoJl c‘zchonfjfihwtlj H is 2.| or 2.2. C. \J 2.5 surelj C". is 772.5 CLIEBK your: more ehdran—retzas’mj than H. “\Cfi C+ on?“ MHhZSL 60371.0?! H // ’2- 5 H see FE 3.53—4.15 Marz- CA—rbOCA‘l'lbns (form fASEEr‘ +//M ,' \ KCHL inécrmea'. . + " 22cm _ a new E Raci- / mechanisM SN 2 (Mack $2. Ere see sec.” . ea 8-3 W375 gala; K25w" ‘35 m M 4 5,42, 86. A; 2.3%; + " l meg = lg [acuzouzl [BF] Lyushes owl: OHL ' O‘Hngrhoaj; 6.? Mal;st HAHJes 0..) goH + sou: —-a RCL+ sol-r HCL 1. 1°." 2° wbrhs we.“ X2 = 0!; MA). {if-2,. doesn‘i' work... XL = IL CaM‘i’ ‘96.. con4¢0H¢6 X2”: F2 Yeac—Hon C) goes Hmij radicd tnfirmdques @ fi— fHMs can be. seen 'm- bancl dissoc.enz:j|es (31355 see. ’(Amb 4.3)701‘ {Odie/r; Nb Wowt), _' ) carbon mi?“ 3 ‘00an and an odd etecbran SEAN“? series sauna as aw odA‘EtbnS 3°~--2°~--1°---~C|‘!3 mar-E .leasl: SN) LC— 5%“ t——-— c—Br C-_CL CH3‘CH3 “a 0:32:44Z + .H 93 1° 4,9 81.5 0 o (CH3)ZCHL -—-? (Chg)ch + . H 95 68 . 5 > 1 ° 63 . (“93% “‘7 (@930 + -l-( 91 3 fl—Io “5M3 335$ 430' dekrwu'ne. 61C areachém (MW—yd J (333% W accuf. . B?“ . l I r (MSG-{20+3 + 'Br-a -‘—--‘> CH3C,HCH3 + HBr— ' bonds broken \oand: {3oer CfiH Bv-Br C—Br H~Br _C.o.$'E' 95 I V ‘46 jau'n -~ 68 815 1 NET =. [4.5 écaJ down/fill! I thus wade! work, . Adud reacHan reguire: lljfif 0" , X2— .,. p“) .5 2 X- (Pho‘fodfssoc (yrokLe’M wf‘HA qtkane, hadogfimk'lnén, sown—Hm {acks seiech‘u;+g7 CH3 CHzCHlCHZCl-g + + ’1‘ wWI.’ x I \/\ —+ a; M“ Y\ ivfi'HaL groiudzs 23% {(2.0 h? _ \/\ + 3.1 .4, 2% . 98/0 buf cm also 813; foBkQIOWA-Eén [101,315 BYL We sated-{‘03, them (1L? égf‘fJ’IZ-B [10% are. 2° silxs fiuwec‘ over 1° Lawn ‘H’loujL Prkué C—X 3“” agar 'erm Z°c—x V. III-11 “Quit +0 cmstex' 5&4): ‘) hm; A-‘l‘l,fl‘L_./ ' \ . V " .. 2,) ~C-H -v ‘X: --_-——-, ’ ..\co' 4- H-X = - i -- / °' 0 k‘ 3)?voptjh‘ham "‘“--‘~-.‘ \ to )C. .g. x2 —-—-—> :C—X ‘. erlds product and +0 CDK‘h‘KMLIC'AaI'n SR? 2) should be. source of SL‘QC‘E‘UIH quZ-b3 AeELr-mhu: overall awerje‘lfics once. X- avail/\le firX=Br 3, .- + CHSCHZCHS -——9 HBr + (cagzéu '3, . - c1+3cx4ch3 -——-> HBr + -CHz-CHz-CH3 «3.5 kcal ark?“ far X=CJ I both“ are. domnk?“ 8 Md. Shunt! ...
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Lecture Notes 4 - Choir. '4 312,1. «nut 4dlow atukb fin...

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