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Week+8+Worksheet+Answers

Week+8+Worksheet+Answers - Organic Chemistry II Week 8...

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Unformatted text preview: Organic Chemistry II Week 8 worksheet Not for credit Identify each molecule below by whether the amine is primary, secondary or tertiary, and whether it is aiiphatic, heterocyclic or heterocyclic aromatic / heteroaromatic. NHZ - H N \ N G \1 I N 2 Q N \l/ Steam do. rj hQ+MOQPDMK4tlL “P elm oJ‘S "(Leer-Ha. :9 ‘ NH2 her-erocbrc {r'c ‘ bk ' / . h ~ Pr i m CL 1‘ a aroma EC. 61 (p a+rc auphayfllc C ban 1—3 I) _ Place each of the following compounds in order of increasing boiling point and increasing water solubility: i ‘_ ‘ O 7‘ r ‘. I O \/\ i ‘ \)J\ \/\OH . NH2 OH H ['o wzsl‘ l lob AC)?” —-> fill "—9 WMHZ“? \/\Ot+ h"? AQH ldafilo'j ?Ka'-7. l teem-{ad 0” 5 ““Hf 0- S? NH2 0H ' NH3+ 0' é‘-—— precinct-5 fl + w + + = + ‘ N02 N02 N02 N02 I! :7 ‘f ‘ , (a 7.: 9K“: IO ?%H H H 0' Kasgr 2- P OH H 0“ n ? N 41408 \N{ P N Bea Chm H; I!“ I \ +—- \ + ‘1‘“ + l + = l + / / I no2 ' N02 no2 7 N02 Show the two reactions necessary from 4—methylbenzyi bromide to prepare the product shown where n=1. Then show how the same starting material can be used to prepare the product where n=2. IB’ _-__ ____ __,_ 11 “Hz ET?“- ems flew/Hr @sr‘v— QJ/fi'o 1 of 2 W @M a w 2) 7412C) “— j: cam). 0 1) (CH3)2NH, w 7 4%”; la wc ——--—-‘—‘—D- 2) HZINE Covet/e cf (Ed/(ACHDVL 5% 64’: am mas ‘ 1) $0012 2) (CH3)2NH -——-———>- 3) LiAlH4 4) H20 OH “H2 ‘ 1) NaNOz, HCI 2) KCN, CuCl ' —-"--—-—F- 3) LiAlH4 4) H20 1) HNO3, 142304 '—'——D'- 2) H2/Ni “H2 1) NaNOz, HCI '—'—-" - 2) HCI, 0110! 1) (EXCESS), K2003 ——>— / T A920, H20 OH 3) heat 7 Hoflman g Mnhafl'm 2 of 2 ...
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