Week+8+worksheet

Week+8+worksheet - how the same starting material can be...

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1 of 2 Organic Chemistry II Week 8 worksheet Not for credit Identify each molecule below by whether the amine is primary, secondary or tertiary, and whether it is aliphatic, heterocyclic or heterocyclic aromatic / heteroaromatic. N N N NH 2 NH 2 H N Place each of the following compounds in order of increasing boiling point and increasing water solubility: O H O OH NH 2 O OH Identify whether each reaction below would favor the reactants or the products at equilibrium. The pKa of p-nitrophenol is 7.1. OH NO 2 + NH 2 O - NO 2 + NH 3 + OH NO 2 + NH 2 O - NO 2 + NH 3 + OH NO 2 H N + O - NO 2 N + + H H OH NO 2 N + O - NO 2 N + + H Show the two reactions necessary from 4-methylbenzyl bromide to prepare the product shown where n=1. Then show
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Unformatted text preview: how the same starting material can be used to prepare the product where n=2. NH 2 n Br 2 of 2 1) NaN 3 2) H 2 O 3) LiAlH 4 4) H 2 O Br 1) (CH 3 ) 2 NH, H + 2) H 2 /Ni O 1) SOCl 2 2) (CH 3 ) 2 NH 3) LiAlH 4 4) H 2 O O OH 1) NaNO 2 , HCl 2) KCN, CuCl 3) LiAlH 4 4) H 2 O NH 2 1) HNO 3 , H 2 SO 4 2) H 2 /Ni O OH 1) NaNO 2 , HCl 2) HCl, CuCl NH 2 1) CH 3 I (excess), K 2 CO 3 2) Ag 2 O, H 2 O 3) heat N...
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This note was uploaded on 01/22/2012 for the course CHEM II taught by Professor G during the Fall '11 term at Berkeley.

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Week+8+worksheet - how the same starting material can be...

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