CC bond objectives

CC bond objectives - • Describe the effects of...

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Organic Chemistry II UC-Berkeley Extension, Fall 2011 Week 9: Diels-Alder reaction, diene and dienophile, aromatic transition states, Claisen rearrangement, Cope rearrangement, Heck reaction, Suzuki coupling, alkene/olefin metathesis, synthesis of single enantiomers. Objectives: Draw the products of the carbon-carbon bond forming reactions we have learned previously. Draw the products of a Diels-Alder reaction, including the endo/exo configuration of products. Draw the mechanism for the Diels-Alder reaction and explain the basis for the preference of an endo configuration in the final product.
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Unformatted text preview: • Describe the effects of electron-donating and electron-withdrawing substituents on the reactivity of the diene and the dienophile. • Draw the products of the Cope rearrangement and the Claisen rearrangement. • Draw the products of the palladium-catalyzed reaction of an organohalide and an alkene in a Heck reaction. Show the correct stereochemistry around the double bond(s) in the product. • Identify the products of the palladium-catalyzed Suzuki reaction of a boron derivative with an organohalide. Page 1 of 1...
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