Review_Exam_1_2011 - Chemistry 341 Physical Chemistry I...

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Chemistry 341 Physical Chemistry I Fall 2011 EXAM 1 REVIEW SHEET [Exam 1: Friday September30, 11:10 AM–12:00 PM, Packard Lab Aud. 101] Quantum Mechanics 1. Wave theory of light constructive interference destructive interference 2. Planck quantum theory blackbody radiation ( ) ρ ν π ν ν ν = 8 1 2 3 c h e h kT average energy of an oscillator ε ν ν = h e h kT 1 3. Photoelectric effect k e m v h e . . = = 1 2 2 ν φ 4. de Broglie relation λ = h p 5. Wave behavior in 1-D wavelength ( λ ) wavenumber ( ~ ν λ = 1 ) period ( τ ) frequency ( ν τ = 1 ) 6. Differential equation for the spatial dependence of a standing wave d dx D D 2 2 2 2 = − π λ 7. Schrödinger equation in 1-D + = h 2 2 2 2 m d dx V E ψ ψ ψ
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8. Eigenvalue problem $ Λ ψ λ ψ = ψ is an eigenfunction of the operator $ Λ with eigenvalue λ 9. Heisenberg uncertainty principle x p h 2 10. Three postulates concerning quantum theory 11.
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