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Chapter 15 Templates

Chapter 15 Templates - Chapter15: AromaticCompounds...

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1 Chapter 15: Benzene and Aromaticity Aromatic Compounds: Examples: Unsaturated cyclic systems that undergo substitution rather than addition
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2 I. Nomenclature: IUPAC System Monosubstituted benzenes: Examples: If the alkyl substituent is the same size or smaller than the ring (six or fewer carbons), the compound is named as an alkyl substituted benzene If the alkyl substituent is larger than the ring (more than six carbons), the compound is named as a phenyl substituted alkane
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3 Different ways to indicate benzene and benzene containing groups as substituents: Phenyl group: Benzyl group: Examples: Different ways to write/draw benzene and benzene containing groups: ,
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4 Naming disubstituted benzenes: General orientation of groups: Examples:
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5 Naming benzenes with more than two substituents: Examples:
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6 Assigning Common Names: Examples:
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7 Structural Characteristics and Stability of Benzene: Predicted Stability Based on Heats of Hydrogenation
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8 Observed Reactivity: Addition of Bromine Why?
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9 Localized or Uniform Electron Distribution: Bond Lengths: Electrostatic Potential Map Alkanes: Alkenes: Benzene:
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