CHEM 2212 Chapter 23 Templates

CHEM 2212 Chapter 23 Templates - Caveats and Limitations:...

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1 Chapter 23: Carbonyl Condensation Reactions Previously discussed carbonyl reactivity patterns:
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2 Carbonyl Condensations: The Aldol Reaction General Reaction: Examples (symmetrical):
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3 Carbonyl Condensations: The Aldol Reaction Mechanism:
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4 The Aldol Condensation: Equilibrium The aldol reaction is reversible Example: Example:
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5 Carbonyl Condensation versus Alpha­Substitution: Example:
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6 Conditions for Condensations: Example:
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7 Dehydration of Aldol Products: Synthesis of Enones General Example:
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8 Base Catalyzed Dehydration Mechanism: Acid Catalyzed Dehydration Mechanism:
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9 Shifting the Aldol Equilibrium General Example:
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10 Practice:
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11 Mixed (Asymmetric) Aldol Reactions Examples:
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12 Practice Problems:
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13 Practical Mixed Aldol Reactions Examples:
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14 Mixed Aldols with Acidic Carbonyl Compounds Example:
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