RxnSummary2 - H2CrO4 R 1o ROH OH or Na2Cr2O7 /H2SO4 or...

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R OH H 2 CrO 4 R OH O or Na 2 Cr 2 O 7 /H 2 SO 4 or CrO 3 /H 2 SO 4 1 o ROH Carboxylic Acids R R' H 2 CrO 4 R R' O or Na 2 Cr 2 O 7 /H 2 SO 4 or CrO 3 /H 2 SO 4 2 o ROH Ketones OH R OH PCC or PDC R H O 1 o ROH Aldehydes CH 2 Cl 2 R R' R R' O 2 o ROH Ketones OH PCC or PDC CH 2 Cl 2 RO H Na o or K o ROH (solvent) Na H NaH ether; THF or alkanes Na 2 2H 2 + (reaction is irreversible)
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R R'' HX 3 o ROH 3 o Halides OH R' R R'' X R' R R(H) HX (conc) 1 o &2 o ROH OH H R X H 1 o o Halides Heat N R SOCl 2 1 o o ROH OH H R Cl H 1 o o Chloride Pyridine or N(Et) 3 CH 2 H 3 O + OH R ROH -H 2 O CH R Alkene (Zaitsev's rule) R O R' Ether R OH ROH 1) Na o 2) R' X 1 o or 2 o
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RO H H OR' R OR' H 2 SO 4 Heat + CC H 2 R R H OR' H 2 SO 4 Heat + C CH 2 H R R OR' H 2 H 2 O 2 Ag H 2 R R RCO 3 H CH 2 Cl 2 H 2 H 2 O 2 2 H 2 O R R H 2 R R NaOH H 2 O R R X O H H 2 O R R H 3 O + H 2 O H R R OH
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CC H 2 O (H)R R H 2 O H (H)R R CN Na + CN - H 2 O H 2 O (H)R R H 2 O H (H)R R C 1) Na + 2) H 2 O H CH H 2 O (H)R R H 2 O H (H)R R NH 2 NH 3 Second Semester H 2 O (H)R R H 2 O H (H)R R R" Mg Chap 15: RX etherorTHF R Mg X X Mg Mg Br R" Mg X 1) 2) H 3 O +
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C O R(H) R R" Mg X 1) 2) H 3 O + C O H R(H) R R" R' X + R 2 CuLi R' R
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RxnSummary2 - H2CrO4 R 1o ROH OH or Na2Cr2O7 /H2SO4 or...

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