Chem 240 Final Review with Alkynes and Diels Alder

Chem 240 Final Review with Alkynes and Diels Alder - 9. R,S...

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Chem 240 - Final Exam Review 1. Nomenclature 2. Rotational Diagrams – Newman Projections (see 6f) 3. Boat/Chair Configurations 4. Page of Death – usually 12 of them 5. Syntheses – make two compounds from a selection of five 6. Mechanisms a. Fisher Ester forwards and backwards b. Acetal forwards and backwards c. SOCl 2 d. Markovikov addition w/ hydride shift e. Halohydrin f. E2 Elimination products – Newman projection g. Free Radical Halogenation (see 12 below) 7. Short answer a. Restrictions on Grignard b. Advantage of SOCl 2 /PCl 3 over HCl c. Why no E2 eliminations on alcohols d. Ingredients for a Williamson Ether synthesis e. Acidity of Alcohols 1º > 2º > 3º and why 8. Table of Rxn Types: SN1, SN2, E1, E2
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Unformatted text preview: 9. R,S configurations, enantiomer/diasteromer pairs 10. Draw Lewis Structure, Hybridization, and bonds 11. Intermolecular forces, H-bond, dipole-dipole, dispersion 12. Free Radical Halogenation and Prediction of Products 13. Alkyne Chemistry and Diels Alder Reactions Synthesis and Reactions of Alkynes Synthesis of Alkynes Reactions of Alkynes O O C C Cl O O O H 3 C C C H Cl O + + + + + 1) Please draw the product of each of the following Diels-Alder reactions. O O C C Cl O O O H 3 C C C H Cl O + + + + + O O O O Cl O O O H 3 C Cl H 3 C Cl H H O Cleaned up structure Cleaned up structure 1) Please draw the product of each of the following Diels-Alder reactions....
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Chem 240 Final Review with Alkynes and Diels Alder - 9. R,S...

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