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thermo1 - Chem 444 Instructor Nancy Makri PROBLEM THERMO1...

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Unformatted text preview: Chem. 444 Instructor: Nancy Makri PROBLEM THERMO1 For a reversible process show the relations: (a) (b) (c) ∂U ∂T − dq = ∂U ∂T ∂U ∂P +P P ∂V ∂T dT + P ∂U ∂P +P T ∂V ∂P dP T = cP − PV α P = PV κ T − (cP − cV ) T where α and κ T spectively. κT α are the coefficient of thermal expansion and isothermal compressibility factor, re- ...
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