348-problem37 - Chem 540 Instructor Nancy Makri PROBLEM 37...

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Chem. 540 Instructor: Nancy Makri PROBLEM 37 A Hamiltonian 0 ˆ H for a three-state problem has eigenvalues equal to 0 ε , 0 ε , and 1 ε . The two degenerate eigenstates are chosen to be orthogonal. A perturbation ˆ V is applied, which has the following matrix elements in the basis of eigenstates of
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