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Ch 6 practice A - CHAPTER 6 1 Which of the following would...

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CHAPTER 6 1. Which of the following would you expect to have the highest boiling point? A) CH 3 CH 2 CH 2 Br D) CH 3 CH 2 CH 2 F B) CH 3 CH 2 CH 2 I E) CH 3 CH 2 CH 3 C) CH 3 CH 2 CH 2 Cl Ans: B 2. What would be the name of the following? CH 3 CH 2 CHBrCHBrCH(CH 3 ) 2 3. What would be the major product of the following reaction? H 3 C CH 3 CH 2 Br H Na + - CN DMSO ? H 3 C CH 3 CH 2 CN H H 3 C CH 3 CH 2 N H C H 3 C CH 3 CH 2 H CN H 3 C CH 3 CH 2 H N C H 3 C CH 3 CH H There you are at it again. Good luck. Did you get it? Page 1
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4. Which of the following would you expect to react fastest with the nucleophile I - (iodide)? 5. Predict the major product of the following reaction: Ph I H KN 3 ? A) Ph N 3 H B) Ph H N 3 C) H Ph N 3 D) N 3 Ph H E) no reaction occurs Ans: B 6. Which of the following would you expect to have the weakest C-X bond? 7. Which of the following haloalkanes would not undergo the reaction below? R-X + CH 3 S - CH 3 SR + X - Hope you can do most of these. Page 2
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8. What is the major product of the following reaction: Br Ph 3 P / DMSO ? PPh 3 Br + - P Br 9. Indicate the reagents required to achieve the following transformation: H CH 3 Br CH 3 CH 3 O H H CH 3 CN CH 3 CH 3 O H ? A) NaCN B) 1) NaF 2) KCN C) 1) NaI 2) NaCN D) 1) NaOMe 2) HCN / light E) none of the above Ans: C Why C? Because the absolute configuration is maintained, you need to inver t it twice.
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