Chapter 8 practiceA

Chapter 8 practiceA - 1. To which side, if any, would the...

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1. To which side, if any, would the following equilibrium lie? H 3 C CH H 3 C OH H 3 C CH H 3 C O - Na + + NaOH + H 2 O A) to the left D) there is no way to tell B) to the right E) this reaction cannot occur at all C) equally to the right and left Ans: B 2. What would be the name of the following compound? HO A) 3-hydroxymethyl-4-methylheptane D) 2-ethyl-3-propyl-1-butanol B) 2- sec -butyl-1-butanol E) 2-( sec -pentyl)-1-butanol C) 2-ethyl-3-methyl-1-hexanol Ans: C 3. What would be the expected product(s) of the following reactions? CH 3 Br C O H ? 1. Mg, ether 2. 3. H 3 O + A) CH 3 OH B) OH H 3 C Page 1
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C) CH 3 HO D) CH 3 HO E) CH 3 H CH 2 OH + Ans: B 4. What would be the major organic product of the following reaction? CH 2 OH H ? K 2 Cr 2 O 7 H 2 SO 4 , H 2 O A) CH 2 B) CHO H C) CO 2 H H D) Page 2
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O E) CH 3 OH Ans: C 5. What would be the expected product(s) of the following reactions? Br ? 1. Mg, ether 2. D 2 O A) C 6 H 5 OH B) C 6 H 5 D C) C 6 H 5 OD D) C 6 H 6 E) both A and C Ans: B 6. Which of the following reactions would produce the alcohol shown? OH A) CH 3 I 1. Mg, ether 2. CH 3 CH 2 CH 2 CH 2 CHO 3. H 3 O + ? B) Br ? 1. Mg, ether 2. CH 3 CHO 3. H 3 O + C) CH 3 CH 2 CH 2 CH 2 C O CH 3 NaBH 4 CH 3 OH ? D) all of these E) none of these Ans: D Page 3
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least miscible with (= least soluble in) water? A) H 3 C CH 2 CH 2 CH 2 OH B) CH 3 H 3 C CH 2 CH OH C) CH 3 H 3 C CH CH 2 OH D) CH 3 CH 3 H 3 C C OH E) all have equal water solubility Ans: A 8. Which of the following reagents would accomplish the reaction shown? O OH ? A) H 2 SO 4 , H 2 O D) HO - , H 2 O B) H 2 CrO 4 E) none of the above C) O 2 (slow) Ans: E 9. Which of the sequences below would accomplish the following transformation? CH
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Chapter 8 practiceA - 1. To which side, if any, would the...

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