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PracticeChapter 13Problems

PracticeChapter 13Problems - 1 What would be the proper...

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1. What would be the proper name of the following compound? H 3 C C C H 3 C C H OH A) 1,1-dimethyl-2-propyn-1-ol D) 2-methyl-3-butyn-2-ol B) 3-methyl-1-butyn-3-ol E) 2-ethynyl-2-propanol C) 3-hydroxy-3-methyl-1-propyne 2. What would be the product of the following reaction sequence? H 3 C C CH ? 1. NaNH 2 2. CH 3 CHO 3. D 2 O CH 2 C CH C H DO CH 3 H 3 C C C C CH 3 OD H CH 2 C CD C H HO CH 3 3. What would be the product of the following reaction? CH 2 C C H ? H 2 O cat. H 2 SO 4 cat. HgSO 4 CH 2 CH 2 C O H Page 1
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CH 2 C C OH CH 2 CH CH 2 OH OH CH 2 C CH 2 OH O CH 2 C CH 3 4. What would be the product of the following reaction? CH 2 CH 2 CH 2 CH 3 CH 2 C C CH 3 H H CH 2 C C H Page 2
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CH 2 C C CH 3 H H CH 2 CH 2 CH 2 CH 3 5. What would be the product of the following reaction sequence? CH CH 1. Br 2 2. excess NaNH 2 ? A) C C Br Br Ph H Ph H (racemic) B) C C Br Br Ph H Ph H (meso) C) Ph C C Ph D) CH C Br Ph Ph E) CH CH NH 2 NH 2 Ph Ph 6. Given separate pure samples, in what way(s) could you quickly distinguish between the two alkynes below? C C D C C H and Page 3
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