PracticeChapter 23

PracticeChapter 23 - 1 What would be the organic product of...

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1. What would be the organic product of the following reaction? H 2 C O CH 2 O O O O O H 3 O + heat ? A) 2 HO 2 CCH 2 CO 2 H B) 2 CH 3 C(=O)CH 3 C) 2 CH 3 CO 2 H D) HO 2 CCH 2 C(=O)O 2 CCH 2 C(=O)O 2 CCH 2 CO 2 H E) No reaction occurs Ans: C 2. What product would result from the following reaction sequence? H 3 C C CH 2 C O O OCH 2 CH 3 1. NaOCH 2 CH 3 2. C 6 H 5 CH 2 Br 3. H 3 O + , heat ? A) H 3 C C CH 2 O C 6 H 5 B) HO C CH 2 O CH 2 C 6 H 5 C) HO C CH 2 O C 6 H 5 D) H 3 C C CH 2 O CH 2 C 6 H 5 E) H 3 C C CH C O O OCH 2 CH 3 CH 2 C 6 H 5 Ans: D Page 1
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3. To which side, if any, would the following equilibrium lie? O O OH O A) To the left D) Reaction cannot occur at all B) To the right E) Equilibrium favors a different product. C) Equally to the left and right Ans: B 4. Which of the following would be the most acidic? A) O B) CH 3 CH 2 CO 2 CH 3 C) O O D) O O E) O CH 3 Ans: D 5. Predict the products of the following reaction. CO 2 H CO 2 H O ? heat A) CO 2 H O Page 2
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B) CO 2 H O CO 2 H + C) CO 2 H D) O E) none of these Ans: D 6. What would be the expected product of the following reaction sequence? H 3 C C O OCH 2 CH 3 1. CH 3 CH 2 O - Na + 2. H 3 O + (no heat) ? A) H 3 C CH 2 OCH 2 CH 3 O O B) H 3 C O OCH 2 CH 3 O O C) H 3 C C CH 2 C OCH 2 CH 3 OH O H D) H 3 C C O OH E) Page 3
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CH 3 CH 2 O C O C O OCH 2 CH 3 Ans: A 7. What factors contribute to the stability of the following structure? H 3 C C C C CH 3 O HO H A) structure has a 6 π electron aromatic system. B)
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This note was uploaded on 02/07/2012 for the course ECON 122 taught by Professor Staff during the Spring '11 term at Rutgers.

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PracticeChapter 23 - 1 What would be the organic product of...

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