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Exam_2_Fall-2010_Key - E/o'^Z keu l(6 pts Complete the...

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E/o'^Z- keu (6 pts) Complete the names of the following ff*, by labeling them E or Z. ,trt t er,,"lL l. ( l)-a-etnyl-5-isobutylnon-4- ( 7)-2-(bromomethyl)-1- ene chloro-3 ,3 ,3-trifluoroprop- I -ene 2. (6 pts) Rank the following compounds in terms of stability. ( ( E) -3 - cy clopropyl-4-methyl- 2-propylpent-2-en-1-oI t w ) Pts = Jet r=most stable) rtc 07 )roL tilLt 3 a 3. (6 pts) Rank the following alkenes in terms of their rate in hydration reactions catalyzedby H2SO4. (l= fastest,3 = slowest) trB *09t* tst oy Jrl rjtb
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4. (25 pts) Fill in the boxes with the appropriate starting material or product(s). a td, Cr S fu:l / r + O {o-alk.rn€ J + Bt2in C}JzClz I €" +& --- ci1 \ brar.f ( tsr dttrzr + /; \,^- *,T.)"r'-l: U 1o Frr + | f.^l. b. \3'r" * lCD' + 1. OsOa 2. NaHSO3 + I eq. HBr *2fi'r orti /1 /t1\ k'r * +5 +/ rro {o.- X r& W +z fn+ -t- Brr I ""tt- I Br +] fr) +5 G) t 2 G{- no*.S cd t),:'"'J + 3 ;f q pi hzri Zz S*ereo c # 1. BH3 2.}lO-lH2O2 Hzo + HgSOa H2S04 + 4Fo. AloH (, r3ro- tci(r; ^n st.;,r\ tr +3 rr) r f tz) q, t, +'t^;s B;*< n^l+ip[u p"il*^da
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5. (6 pts) Rank the following radicals in terms of their stabili ity.
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