PS_4-Key - Problem Set#4 Swager 5.12 Due Friday September...

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Unformatted text preview: Problem Set #4 Swager 5.12 Due Friday September 30 at 4PM 1. Rank the following conformations in order of increasing energy. THKCHL'J: H3 Amped“ HfCH} e T é; 2. Designate the following compounds as R or S. 3 HI H30,“ Cch2 K H c:H2c:H3 a 52 S 3. Draw the most stable conformations of the following cyclohexane derivatives. Which one is most stable? 4. How is each molecule (1—4) related to compound A? (constitutional isomer, stereoisomer, identical) OH OH NH; 5. Which of the following compounds is (are) chiral? 6. Draw mirror images of each of the following molecules and indicate if they are chiral or achiral. CH3 : C lg i H3001,“ / ‘ v \\\C"’3 v (c = C :0 t / N H 1 H ‘ / 7. In the reaction sequence given which step will have the highest activation energy? Sketch out reaction coordinate energy diagram with the different species (A, B, C, D) labeled Cl H36 CH3 ‘06 ’ + HCl Step 1 Step 2 Step 3 C ...
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