Problem_Set__3

Problem_Set__3 - O H 3 C CF 3 O H 3 C CF 3 O F 3 B (CH 3...

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Problem Set #3 Swager 5.12 (Due Friday, September 23 at 4PM) 1. Consider the following acid-base reactions. Predict which direction the equilibrium will favor (left or right). OH + O + + O O + O O O O H O O + O O O OH + 2. Rank the acidity of the labeled protons (A-E) in the following molecule from lowest to highest acidity. Explain your reasoning. C H 2 C H 2 C H 2 CF 3 O O O CH 2 H 3 C A B C D E
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3. Rank the in terms of pKa the following molecules. Explain your answers. H 3 C CF 3 O H 3 C CH 3
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Unformatted text preview: O H 3 C CF 3 O H 3 C CF 3 O F 3 B (CH 3 O)F 2 B 4. Rank the following in terms of their Lewis acid and Lewis base strengths. Cl Al Cl O Cl Al O O Cl Al O O Cl Al O O O H N O O 5. Draw Newman projections of the following molecules along the different axes given. . OH H N 6. Provide three-dimensional line drawings of the following Newman structures. H 3 C F Cl H OH H H NH 2 CH 3 H H F...
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Problem_Set__3 - O H 3 C CF 3 O H 3 C CF 3 O F 3 B (CH 3...

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