Intro 1.2

Intro 1.2 - MSE 3050: Thermodynamics Phase Diagrams...

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MSE 3050, Thermodynamics and Kinetics of Materials, Leonid Zhigilei MSE 3050: Thermodynamics – Phase Diagrams – Kinetics Review of classical thermodynamics First Law - Energy Balance o Thermodynamic functions of state o Internal energy, heat and work o Types of paths (isobaric, isochoric, isothermal, adiabatic) o Enthalpy, heat capacity, heat of formation, phase transformations o Calculation of enthalpy as a function of temperature o Heats of reactions and the Hess’s law Theoretical calculation of the heat capacity o Principle of equipartition of energy o Heat capacity of ideal and real gases o Heat capacity of solids: Dulong-Petit, Einstein, Debye models o Heat capacity of metals – electronic contribution Entropy and the Second Law o Concept of equilibrium o Reversible and irreversible processes o The direction of spontaneous change o Entropy and spontaneous/irreversible processes o Calculation of entropy in isochoric and isobaric processes o Calculation of entropy in reversible and irreversible processes
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MSE 3050, Thermodynamics and Kinetics of Materials, Leonid Zhigilei MSE 3050: Thermodynamics – Phase Diagrams – Kinetics
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Intro 1.2 - MSE 3050: Thermodynamics Phase Diagrams...

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