Lect18_1003 - trans-1,3-Dimethylcyclohexane exists as a...

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their discoveries concerning the activation of innate immunity 2011 Nobel Prize in Physiology or Medicine Bruce Beutler Ralph Steinman Jules Hoffmann
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Ch. 5 - 2 13. Fischer Projection Formulas 13A. 13A. How To How To Draw and Use Fischer Draw and Use Fischer Projections Projections H 3 C Ph COOH HO Et Br Et OH Br Ph CH 3 COOH Et OH Br Ph CH 3 COOH Fischer Projection
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Ch. 5 - 3 14. Stereoisomerism of Cyclic Compounds Plane of symmetry a meso compound achiral Me H Me H H Me H Me mirror enantiomers
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Ch. 5 - 4 14A. 14A. Cyclohexane Cyclohexane Derivatives Derivatives 1,4-Dimethylcyclohexane Plane of symmetry •B o t h cis -& trans- 1,4-dimethylcyclo- hexanes are achiral and optically inactive •T h e cis& trans forms are
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Ch. 5 - 5 1,3-Dimethylcyclohexane Plane of symmetry cis-1,3-Dimethylcyclohexane has a plane of symmetry and is a meso compound
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Ch. 5 - 6 1,3-Dimethylcyclohexane NO plane of symmetry
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Unformatted text preview: trans-1,3-Dimethylcyclohexane exists as a pair of enantiomers Ch. 5 - 7 1,3-Dimethylcyclohexane Has two chirality centers but only three stereoisomers Ch. 5 - 8 15. Relating Configurations through Reactions in Which No Bonds to the Chirality Center Are Broken If a reaction takes place in a way so that no bonds to the chirality center are broken , the product will of necessity have the same general configuration of groups around the chirality center as the reactant Ch. 5 - 9 Same configuration Same configuration Ch. 5 - 10 16. Separation of Enantiomers: Resolution Resolution separation of two enantiomers Ch. 5 - 11 17. Compounds with Chirality Centers Other than Carbon Ch. 5 - 12 18. Chiral Molecules That Do Not Possess a Chirality Center Allene...
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Lect18_1003 - trans-1,3-Dimethylcyclohexane exists as a...

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