Lect29_1102 - Chapter 10 Radical Reactions Ch. 10 - 1 1....

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Ch. 10 - 1 Chapter 10 Chapter 10 Radical Reactions Radical Reactions
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Ch. 10 - 2 1. Introduction: How Radicals Form and How They React Heterolysis ions Homolysis radicals
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Ch. 10 - 3 Production of Radicals Production of Radicals Homolysis of covalent bonds Need heat or light (h )
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Ch. 10 - 4 Single-Bond Homolytic Dissociation Energies (DH°) at 25°C Bond Broken kJ/mol H F5 7 0 H Cl 432 H Br 366 H I2 9 8 2. Homolytic Bond Dissociation Energies (DH°)
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Ch. 10 - 5 Single-Bond Homolytic Dissociation Energies (DH°) at 25°C Bond Broken kJ/mol Bond Broken kJ/mol H 3 C H4 4 0 H 3 C F4 6 1 H 3 C Cl 352 H 3 C Br 293 H 3 C OH 387 H 3 C I2 4 0 H 3 C OCH 3 348
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Ch. 10 - 6 Single-Bond Homolytic Dissociation Energies (DH°) at 25°C Bond Broken kJ/mol Bond Broken kJ/mol 354 294 355 298 349 292 Cl Cl Cl Br Br Br
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Ch. 10 - 7 Single-Bond Homolytic Dissociation Energies (DH°) at 25°C Bond Broken kJ/mol Bond Broken kJ/mol 423 369 413 465 400 474 375 547 H H H Ph H H H Ph H CH HC
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Ch. 10 - 8 2A.
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Lect29_1102 - Chapter 10 Radical Reactions Ch. 10 - 1 1....

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