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Take Home Assignment 1.3

Take Home Assignment 1.3 - Aldol Condenation Reaction Show...

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CHEM 334 S PRING 2011 T AKE -H OME A SSIGNMENT 3 U NIT 1 Name:________________ TA:__________________ Please return to your TA on Thursday, 2/3/2011 before Exam 1.
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1. How might you bring about the following conversion? 2. Cyclohexene can be converted to a 1-cyclopentenecarbaldehyde by the following series of reactions. Propose a structural formula for each intermediate compound. 3. Draw structural formulas for the products of each crossed aldol reaction and for the compound formed by dehydration of each aldol product. 4. Propose a structural formula for compounds A & B . 5. Show retrosynthetically how you would synthesize the molecule shown via the
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Unformatted text preview: Aldol Condenation Reaction . Show all of the relevant intermediate compounds, conditions, reagents, and starting compound(s). 6. Show retrosynthetically how you would synthesize the molecule shown via the Robinson Annulation Reaction. Show all of the relevant intermediate compounds, conditions, reagents, and starting compound(s). 7. Show a detailed stepwise mechanisms for Part A and Part B of the above transformations. Draw the structures of 1 & 2 . All intermediate compounds, reagents, and conditions must be shown. Formal charges should be indicated....
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