Hybridiz

Hybridiz - 3 s + √ f8e5 2 √ f8e5 3 p x Ψ 2 = 1 √...

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Hybridization A bond will be formed in the direction in which maximum overlapping of orbitals occurs. (L. Pauling) Mix n AO's to get n hybrids Orthonormal set of Atomic Orbitals equivalent in extent, differing in orientation sp Ψ 1 = 1 f8e5 2 ( s + p ) Ψ 2 = 1 f8e5 2 ( s - p ) Ψ 2 1 d τ= 1 2 s 2 + 2sp + p 2 d τ=1 Ψ 1 Ψ 2 d τ= 1 2 ( s + p )( s - p ) d τ= 1 2 s 2 - p 2 d τ=0 sp 2 Ψ 1 = 1 f8e5
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Unformatted text preview: 3 s + √ f8e5 2 √ f8e5 3 p x Ψ 2 = 1 √ f8e5 3 s - 1 √ f8e5 6 p x + 1 √ f8e5 2 p y Ψ 3 = 1 √ f8e5 3 s - 1 √ f8e5 6 p x- 1 √ f8e5 2 p y sp 3 Ψ 1 = 1 2 ( s + p x + p y + p z ) Ψ 2 = 1 2 ( s – p x + p y – p z ) Ψ 3 = 1 2 ( s + p x – p y – p z ) Ψ 4 = 1 2 ( s – p x – p y + p z ) x y z...
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This document was uploaded on 02/22/2012.

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