RoSymm

RoSymm - Rotational Spectroscopy- Symmetric Tops Classical:...

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Rotational Spectroscopy- Symmetric Tops Classical: E = J 2 x 2I xx + J 2 y 2I yy + J 2 z 2I zz H H H Cl z x y I yy = I xx = I I zz = I  E = 1 2I (J 2 x + J 2 y ) + 1 2I  J 2 z E = 1 2I (J 2 x + J 2 y ) + 1 2I J 2 z + 1 2I  J 2 z 1 2I J 2 z E = J 2 2I + 1 2I  1 2I J 2 z J 2 = J 2 x + J 2 y + J 2 z J 2 = h 2 (J(J+1)) J z = K h K = 0, ± 1, ± 2,. .. ± J F ~ JK = B ~ J(J+1) + (A ~ – B ~ )K 2 B ~ = h 4 π I c A ~ = h 4 π I  c dipole moment parallel to figure axis ( = handle)
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This document was uploaded on 02/22/2012.

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