SpectFormulas

SpectFormulas - Spectroscopy Light h h = B= 4Ic 4r2c ~ tr =...

Info iconThis preview shows page 1. Sign up to view the full content.

View Full Document Right Arrow Icon
Spectroscopy Light μ =-e r μ = -e Ψ * r Ψ d τ μ tr = Ψ f * r Ψ i d τ μ tr = μ elec Ψ v' Ψ v d τ B ~ = h 4 π Ic = h 4 πμ r 2 c F ~ J = E J hc = B ~ J(J+1) E J = B ~ hc J(J+1) F ~ J = B ~ J(J+1) – D ~ [J(J+1)] 2 D ~ = 4B ~ 3 ν ~ 2 o I = m i r i 2 = μ r 2 E υ = h ν e ( υ + 1 / 2 ) = h ϖ e ( υ + 1 / 2 ) G ~ υ = ν ~ e ( υ + 1 / 2 ) ν ~ e = ν e c in cm -1 G ~ = ν ~ e ϖ e = k μ μ = m 1 m 2 m 1 +m 2 E υ = h ν e ( υ + 1 / 2 ) – χ e h ν e ( υ + 1 / 2 ) 2 + Y e h ν e ( υ + 1 / 2 ) 3 + . ... V = D e (1 - e –a(R-Re) ) 2 a = ϖ e μ 2D e 1 / 2 χ e = a 2 h 2 μϖ e = h ϖ e 4D e = ν ~ e 4D ~ e E υ = h ν e ( υ + 1 / 2 ) – χ e h ν e ( υ + 1 / 2 ) 2 h ν o = hc ν ~ e – 2hc ν ~ e χ e E = h ν e - χ e h ν e 2( υ + 1) G ~ = ν ~ e - ν ~ e χ e 2( υ + 1) D e = D o + 1 / 2 h ν e - 1 / 4 χ e h ν e D ~ e = D ~ o + 1 / 2 ν ~ e - 1 / 4 ν ~ e χ e E υ ',J' <– υ ,J = E υ ',J' E υ ,J = h ν o ( υ ' - υ ) + B ~ ' hc J'(J'+1) – B ~ hc J(J+1) B ~ υ =B ~ e -
Background image of page 1
This is the end of the preview. Sign up to access the rest of the document.

This document was uploaded on 02/22/2012.

Ask a homework question - tutors are online