TSGibbs

TSGibbs - a = ∆ U o-≠ RT Gases ∆ H o-≠ = ∆ U...

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Thermodynamic Transition State Theory A + B -> [AB] -> products d[A] dt = k 2 [A][B] K c = [AB] [A][B] k 2 = kT h RT P o - K p reaction progress A + B products G G Gibbs Free Energy G o - = - RT ln K p k 2 = kT h RT P o - e - G o - /RT G o - = H o - - T S o - k 2 = kT h RT P o - e S o - /R e - H o - /RT Arrhenius Law: ( lnk 2 T ) V = E a RT 2 ln kT h +lnV o - - G o - RT T V = E a RT 2 1 T + U o - RT
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Unformatted text preview: a = ∆ U o-≠ + RT Gases: ∆ H o-≠ = ∆ U o-≠ + ∆ n g RT ∆ n g = -1 E a = ∆ H o-≠ + 2RT k 2 = kT h       RT P o-e 2 e ∆ S o-≠ /R e-E a /RT k 2 = A e-E a /RT A = kT h       RT P o-e 2 e ∆ S o-≠ /R "normal" A = = 10 10- 10 11 L mol-1 sec-1 ∆ S o-≠ = - 80 J mol-1 K-1...
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