{[ promptMessage ]}

Bookmark it

{[ promptMessage ]}

Practice_Final_Chem_3045

Practice_Final_Chem_3045 - Ph=phenyl 3 H 3 O AlCl 3 Cl O 1...

Info iconThis preview shows pages 1–4. Sign up to view the full content.

View Full Document Right Arrow Icon
Practice Final Chem 3045: 1) Write the mechanism for the bromination of cyclohexane. 2) Propose a mechanism for the following: O H 2 SO 4 3) Write the product(s) of the following reactions paying attention to regio- and stereochemistry where applicable. O O O O O O 1 eq. O O 1) O 3 , CH 2 Cl 2 , -78 o C 2) Zn, CH 3 COOH 1) Hg(OAc) 2 , MeOH 2) NaBH 4 HBr 1) BH 3 2) HOOH/OH - /H 2 O HBr, ROOR
Background image of page 1

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full Document Right Arrow Icon
NBS, light Br 2 Br 2 OH O O OH Cl 1) 2) H + , MeOH O O OH Cl 1) 2) MeO - Li, NH 3 , ROH H 2 , lindlar 1) NaNH 2 2) CH 3 CH 2 Br 1) NaNH 2 2) CH 3 CH 2 Br 1) R 2 BH 2) HOOH/OH - /H 2 O HgSO 4 , H 2 SO 4 H 3 C I CH 3 S H 3 C Br CH 3 O Br CH 3 O Br CH 3 OH Cl AlCl 3
Background image of page 2
AlCl 3 Cl O AlCl 3 Cl O 1) 2) H 2 NNH 2 , OH - 1) H 2 SO 4 , HNO 3 , heat 2) H 2 , Pd 3) NaNO 2 4) CuCl 1) H 2 SO 4 , heat 2) D 3 PO 4 1) FeBr 3 , Br 2 2) Mg, Et 2 O 3) D 2 O AlCl 3 Cl O 1) 2) PhMgBr
Background image of page 3

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full Document Right Arrow Icon
Background image of page 4
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: Ph=phenyl 3) H 3 O + AlCl 3 Cl O 1) 2) H 2 NNH 2 , OH-3) NBS, light 4) (CH 3 CH 2 )CuLi AlCl 3 Cl O 1) 2) CH 3 MgBr 3) H 3 O + 4) NaH, CH 3 CH 2 Br 4) How would you synthesize the following starting from materials with five carbons or less, benzene, and any other reagents? (Assume ortho and para can be separated.) Cl OH HO OH Br OH O S 5) Show how you would synthesize the products from the given starting materials plus benzene, reactants with 5 carbons or less and any other reagents: O OH O O H 2 N...
View Full Document

{[ snackBarMessage ]}