Elementary Principles 368 - 9.18 b. References : FeO(s),...

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9- 16 9.18 b. References : FeO(s), CO(g), Fe(s), CO g) at 25 C Substance mol) kJ / mol) mol) kJ / mol) FeO 1.00 CO Fe CO 2 o in in out out 2 ( ( ± ( ( ± ( ± ±± ± ± n H n H nH nHnH 0 11 00 22 33 44 −− QH n H n H Q H nH nH X n nX =+ ⇒= + + + + = ⇒=− ξ Fractional Conversion : r o out out in in r o Δ Δ ±±± ±±±±±± (. ) . 1 1 100 1 CO consumed mol CO (1 mol FeO consumed mol FeO consumed mol CO Fe produced : = mol Fe (1 mol FeO consumed mol FeO consumed mol Fe = : ) () ) 1 1 1 1 1 1 1 1 1 20 1 0 3 1 1 =− ⇒=−− =− n n nn n n n CO produced : = mol CO (1 mol FeO consumed mol FeO consumed mol CO 2 2 2 n n 4 1 1 1 1 1 = ) Extent of reaction : CO out CO in CO ν = = = nnn n X 1 ± ,, ,, HC d T i ip i T == z 25 01234 for ± .( ) . ( ) ± . . ) HT T T 6 0 2 2 6 0 2 0 02761 298 2 51 10 298 8 451 0 02761 251 10 + × + + × kJ / mol ± ) . ( ) . ( / / ) ± . . . / ) ± ( ) . ( ) ± .. . ) ± ) . ( ) ± T T T T T T T H 1 62 2 2 1 2 2 2 2 3 52 2 3 0 0528 298 31215 10 298 3188 10 1 1 298 17 0814 0 0528 31215 10 3188 10 0 02761 298 298 8 451 0 02761
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