Chem210-1 F07 Ex2 p05a

Chem210-1 F07 Ex2 p05a - 29 χ29 Αρε τηερε...

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5. The structure on the right represents the general constitutional formula for a family of compounds known as the aldohexapyranoses. O OH OH OH OH HOCH 2 a) How many possible stereoisomeric forms are there for the aldohexapyranoses? (that is, how many stereoisomers exist for compounds with a structure consistent with that shown above?) (4 points) b) The carbohydrate β-∆-γλυχοσε ισανατυραλλψ-οχχυρρινγ συβστανχε εσσεντιαλιν τηε μ εταβολιχ προχεσσεσοφλιωινγ οργανισμ σ-ιτ ισαν αλδοηεξαπψρανοσε, ανδ ιτοχχυρσιν τηε μ οστσταβλε φορμ ποσσιβλε φοραχομ πουνδ ϖιτη τηε γενεραλστρυχτυρε γιωεν αβοωε. Προωιδε βελοϖ αποσσιβλε τηρεε-διμ ενσιοναλστρυχτυρε φορβ-∆-γλυχοσε. (4 ποιντσ
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Unformatted text preview: 29 χ29 Αρε τηερε ανψοτηερ στερεοισομ εριχφορμ σοφαλδοηεξαπψρανοσεσεθυαλιν σταβιλιτψτο τηε στρυχτυρε ψου δρεϖ ιν θυεστιον (β29 ? Ηοϖ δο ψου κνοϖ? (4 ποιντσ 29 2 5 = 3 2 Ο ΟΗ ΟΗ ΗΟ ΗΟ ΗΟΗ 2 Χ ορ Ο ΗΟ ΗΟ ΟΗ ΟΗ ΧΗ 2 ΟΗ (αλλοφτηε συβστιτυεντσμ υστ βε εθυατοριαλ 29 ΨΕΣ -ϖηιχηεωεροφτηε τϖο στρυχτυρεσαβοωε ψου προποσεδ, ιτ220dσμ ιρρορ ιμ αγε (τηε οτηερστρυχτυρε ψου διδν220dτπρεσεντ29 ϖουλδ βε εθυαλλψσταβλε (ατλεαστ ιν ανον-χηιραλενωιρονμ εντ29 !...
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