drill_set9

drill_set9 - HN O -O COO COO-steps O N N HN Br . O-O O...

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Drill Questions (Course 5.13) 1. Predict the major product of the Baeyer Villiger Oxidation below and write a reasonable reaction mechanism. O O key intermediate O - O O O Ar O major product? MCPBA migratory magnitude: tertiary > secondary alkyl 2. Name the key step in the transformation below and draw its reaction mechanism. HN N O O O Br 2 , NaOH; workup H 2 N N H O O O O COOH O H 99% key intermediates
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Unformatted text preview: HN O -O COO COO-steps O N N HN Br . O-O O Hoffmann Rearrangement 3. Draw a reaction mechanism for the transformation below. O O O O O -MeOH MeO key hydride O -O H O--O O -O shift H steps intermediates 4. Draw a reaction mechanism for the following transformation. O O Me O -Me O OEt EtOH EtO workup EtO key intermediates O O-O-O Me steps Me OEt EtO OEt EtO...
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This note was uploaded on 03/02/2012 for the course CHEM 512 at MIT.

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drill_set9 - HN O -O COO COO-steps O N N HN Br . O-O O...

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