Exam3_97An - name Page 1 of 6 1 Which of the following solvents would be best for the reaction of 2-chloro-2-methylpropane with water to give

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name ______________________________ Page 1 of 6 1. Which of the following solvents would be best for the reaction of 2-chloro-2-methylpropane with water to give 2-methyl-2-propanol ? (H 3 C) 3 C-Cl + H 2 O ! (H 3 C) 3 C-OH + HCl (a) dimethylsulfoxide (H 3 CS(O)CH 3 ) (b) hexane (c) methyl alcohol (H 3 (d) carbon tetrachloride (CCl 4 ) (e) all would work equally well 2. Which of the following reagents could be used for the following transformation? OH Cl (a) HCl and peroxides (c) Cl 2 and light (d) SOCl 2 (e) NBS and light 3. All of the compounds below are optically active. Which would undergo nucleophilic substitution with hydroxide to give a racemic product? Br Br Br a) b) c) d) e ) all would give racemic product Br 4. All of the compounds below are optically active. Which would undergo reaction with HBr in the presence of peroxides to give an optically inactive product? Br a) b) c) d) e) all would give optically active product(s) Br 5. (R)-2-bromohexane can be obtained by the reaction of PBr 3 with which of the following compounds?
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This note was uploaded on 03/11/2012 for the course CHEM 220A taught by Professor Sulikowski during the Fall '08 term at Vanderbilt.

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Exam3_97An - name Page 1 of 6 1 Which of the following solvents would be best for the reaction of 2-chloro-2-methylpropane with water to give

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