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lecture92012NOnotes - 1 Pyrrole Sulfonation 2 Treatment of...

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Unformatted text preview: 1 Pyrrole Sulfonation 2 Treatment of Pyrrole with Strong Acid - polymerization 3 Conjugated Polymers Polyacetylene (PAc) H N H N H N N H N H Polypyrrole (PPy) S Polyphenylene (PP) S S S S Polythiophene (PT) * H N H N n Polyphenylene vinylene (PPV) N N n * Polyaniline (PANi) 4 Conjugated Polymer Applications Light Emitting Diodes (OLED) Artificial Muscles Plastic batteries Electronic “Nose”: TNT sensor 5 Acylation – Vilsmeier reaction 6 Acylation – Vilsmeier reaction 7 Acylation – Vilsmeier reaction 8 Bromination 9 Hemoglobin DegraDegradation Bilirubin Yellow breakdown product of heme Heme Van den Bergh Test 10 Chemistry of Indole Lysergic acid diethyl amide (LSD) Tryptophan amino acid 11 Chemistry of Indole 12 Chemistry of Indole – Electrophilic Aromatic Substitution 13 Mannich Reaction 14 Mannich Reaction 15 Furan and Thiophene Propensity to undergo electrophilic aromatic substitution with E+ 16 Furan and Thiophene Propensity to undergo electrophilic aromatic substitution with E+ 17 Furan and Thiophene- Electrophilic Aromatic Substitution Thiophene- 18 Furan and Thiophene- Electrophilic Aromatic Substitution Thiophene- 19 20 ThiopheneThiophene- Desulfurization 21 ...
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