lecture92012WITHnotes - 1 2 Pyrrole Sulfonation 3 Treatment...

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Unformatted text preview: 1 2 Pyrrole Sulfonation 3 Treatment of Pyrrole with Strong Acid - polymerization 4 Conjugated Polymers Polyacetylene (PAc) H N H N H N N H N H Polypyrrole (PPy) S Polyphenylene (PP) S S S S Polythiophene (PT) * H N H N n Polyphenylene vinylene (PPV) N N n * Polyaniline (PANi) 5 Conjugated Polymer Applications Light Emitting Diodes (OLED) Artificial Muscles Plastic batteries Electronic “Nose”: TNT sensor 6 Acylation – Vilsmeier reaction 7 Acylation – Vilsmeier reaction 8 Acylation – Vilsmeier reaction 9 Bromination 10 Hemoglobin DegraDegradation Bilirubin Yellow breakdown product of heme Heme Van den Bergh Test 11 Chemistry of Indole Lysergic acid diethyl amide (LSD) Tryptophan amino acid 12 Chemistry of Indole 13 Chemistry of Indole – Electrophilic Aromatic Substitution 14 Mannich Reaction 15 ...
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This note was uploaded on 03/06/2012 for the course CHEM 302 taught by Professor Sleiman during the Winter '12 term at McGill.

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