problem set 2 solution

problem set 2 solution - c o)J;{e^ D t EA"t^t;d\Yf r@...

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Q1. Indicate the products of the following reactions: c) ozFt ,t---a/ Erbr R"-S excess H2 -------------> Pt MCPBA # H2 Ru- catalyst BINAP
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O^* Hl - . - | ^ -\ R4lrr,^ic. fvrrXiut:o ; H) H3CO Pco 2Hz # Pd 2Hz Lindlars Catalyst K) M) F
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ot+ R"""*bt, SY Modln-{"--" of OH 6ruf s. No rg\,^^+io^,,n' o* Kst,"'9=- ' \/ \J o) P) Pt H Brz ------------> s) MCPBA 2Hz Lindlars Catalyst I
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faflrwr --' ,a r I t- ["a-pub. Hao aSqcEs t' CorboCgna-. o @ ts J+e- AJO R-EfiLTJo^/ tsP *+ o' sb3 batg -" A)o Ea 9f* NOT o- A*a Te"'r;",j $coup J' Ab Et I
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Q2. Draw the major product and provide a detailed mechanism for the follwing reactions: - .-o StraSboen- l,,J r1rH- 3: t{b' I LA \ u.^bre b,^{, Y\A[*C I - | .^^-.-a nrL; ili,"" p,utrot ; subs#db! P-Jo'* n-\ bO"rsc lar S"s- is sfe,rl e,alll S,'o* reuorJi^3
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Unformatted text preview: c o)J;{e^ D t EA"t^t;d\Yf r@ -, Y Enn$t-$ G"q" \h 48. rrr Bf ,BP* Q2. Draw the major product and provide a detailed mechanism for the follwing reactions: ) cl T OR I k#**S,"to"rt.-ryeI p r\ H2 L-/ -----> Pd--J Ro,,ce^it f'1,\ix*urnc-r',oe-{ 11 syv A JJi hr^.o Y"\F-Q2. Draw the major product and provide a detailed mechanism for the follwing reactions: \,'- ---> HC N) --> Pd I, M) f . .\aV Rorl^r'tc-Erry J"^-,- cs 4K frry-J--(-*-qC,f^" ,-1n*. o) e '^'-- -fr=t-\ J ? sl'rrArnr'--- lffily T9*rs ftrosJ e' )H HBr XHa \t -? (Elimination onl ArcD\ *o Potc' j, f t*t 1eoh'tf"p. ^l:,,& sl{3 +J 1-,:': +q_tk, ( r"^a St"Ib nv'4-o ol";^J R) v) Heat (Elimination only) $**t^ er ct ffis*"...
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This note was uploaded on 03/06/2012 for the course CHEM 302 taught by Professor Sleiman during the Winter '12 term at McGill.

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problem set 2 solution - c o)J;{e^ D t EA"t^t;d\Yf r@...

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