CHEM 341 Workshop Questions Week 13 IUPUI

CHEM 341 Workshop Questions Week 13 IUPUI - explain your...

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Name___________________________________ C341 Workshop Section____________________ November 18/19, 2010 Workshop 13 Questions 1. For the following reactions, give the missing reagents/reactant/product(s) in the box(es) and state the type of reaction. If there is stereochemistry, be sure to note it (e.g., syn/anti/random, inversion/racemization/retention, mixture of diastereomers…). a. (CH 3 ) 2 C H 2 SO 4 heat + H 2 O CH 2 b. (CH 3 ) 3 CCHCH 3 OH H 3 O + + + c. d. HCl 0 o C Cl e. HBr no peroxides Br f. 1
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g. H CH 3 H OH H CH 3 h. Br 2 , CHCl 3 Br Br i. peroxyacetic acid O j. 1. O 3 , CH 3 OH 2. (CH 3 ) 2 S H O k. H 3 C CH 3 Br H 2 O ethanol + l. CH 3 (CH 2 ) 4 CH 2 Cl NaCN DMSO 2. Predict the product for each of the following reactions, and then provide a mechanism to
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Unformatted text preview: explain your response. a. 1-bromo-propane reacting with sodium iodide in acetone b. 2-bromopropane reacting with sodium ethoxide in ethanol at 55 o C AND the same rxn without the ethoxide 2 3. Provide the IUPAC name for the following alkynes. a. Cl b. Br c. NH 2 OH 4. Propose reaction conditions in which you would perform the following reactions. Then provide a mechanism for each reaction. a. Generate cis-2-hexene from 2-hexyne b. Generate trans-2-hexene from 2-hexyne 3...
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This note was uploaded on 03/07/2012 for the course CHEM 341 taught by Professor Oh during the Fall '10 term at IUPUI.

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CHEM 341 Workshop Questions Week 13 IUPUI - explain your...

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