Exam+1+Review - o Reduction of ketone(Wolfe...

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Exam 1 Review Chapter 17 Radical Reactions - Halogenations - Allylic bromination - AntiMarknovnikov HBr Chapter 16 Conjugated dienes - Conjugated vs not conjugated - 1,2 and 1,4 addition (kinetic vs thermodynamic conditions) (MECHANISM) o Energy diagrams - Allylic bromination (with NBS) (MECHANISM) - Diels-Alder Reaction (MECHANISM) o Relative rates for different dienes/dienophiles o Effect of substituents on regioselectivity o Stereospecificity (endo favored…alkene geometry determines product) Ch 16 Aromatic compounds - Determine aromatic, non aromatic and antiaromatic - Name benzene compounds and derivatives Chapter 17 Reactions of aromatic compounds - Electrophilic aromatic substitution (Cl, Br, NO 2 , SO 3 H, R, R-C=0) ( MECHANISMS ) - Reactions of the side chains
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Unformatted text preview: o Reduction of ketone (Wolfe Kishner/Clemmenson) o Reduction of nitro group (Sn) o Benzylic oxidation KMnO 4 o Benzylic bromination (NBS) ( MECHANISM )-Reactions of substituted benzene o Ortho/para or meta directors (be able to explain/resonance) o Effect of substituent on rate-Synthesis using benzene as starting material Chapter 19 Carboxylic Acids-Nomenclature of carboxylic acids-Characteristic peaks in IR and NMR-Preparation of carboxylic acids-Jones reagent on primary alcohol- KMnO 4 on benzene side chain - Ozonolysis of alkenes and alkynes-Acidity of carboxylic acids- acid on benzene (EWG/EDG o/p or m effect)- regular acid (inductive effect)-Amino acids (zwitterions at neutral pH)...
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Exam+1+Review - o Reduction of ketone(Wolfe...

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