Test 1 SI sheets page 1

Test 1 SI sheets page 1 - Chem lOSb Kelsey Nandi Tara...

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Unformatted text preview: Chem lOSb Kelsey, Nandi, Tara Ladies and Gentlemen: Welcome! Before we begin, we’d like to take a moment to tell you how excited we are to be working with you again, as we take on the ChemlOSB beast. I hope you brought your water, sharpened you pencils, and are mentally prepared to shed Ii ht upon the unfathomable dep s of general chemistry in a matter of two hours! Get stoked! si [email protected] gmail.com http://www.usc.edu/si EXAM REVIEW 1 Some stuff to remember... ~ Dr. Parr and Dr. Broyer both have discussion boards where you can post questions © We will accept questions until Weds night at 8:00 PM This test covers different material. . . 0 Dr. Broyer & Dr. Parr: Chapters 1 3~ 14 0 Dr. Warshel: Chapter 13 and 14.1—14.6 2. Consider the following reaction and initial rates: :32 , z {149%} C620“ 2 HgCl2 + C2042- 4: 2 01— + 2 002 + HgQCl? 0 L119: CPL-3‘17 )4 ‘ , " .l° .- . [.3x\os } DIS I" D 5 K 0 Experiment [HgCl2], M [C2042], M Initial Rate, M/s _ m5 -, \ 1 0.105 0.15 1.8 x105 ]” o-‘l‘i; 2 0.105 - 0.30 7.1 x 10-5 3 0.052 )"t 0.15 8.9 x 10-5 WM” 21. Determine the order of the reaction with respect to each reactant and then write the rate law for the reaction. What is the overall order of the reaction? rate- = b [chlaZiECZO‘I omit 0‘1")?!" S 3 1.7195123“ 2"] 2' [03041:] 2 2. b. What is the value oft mare-”— kagc 1: [C204 ; Lax “)5: k (odoSXO-lS) a: Me x163 N1 ...
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