Problem_Set_10_Key - Problem Set 10: Chapter 25 1. Complete...

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Problem Set 10: Chapter 25 1. Complete the following reactions: O HO OH OH OH OH Br 2 , H 2 O O HO OH OH OH CH 3 Cl Ag 2 O C OH H HO H OH OH H CH 2 OH H O H HNO 3 C H H HO HO H OH H CH 2 OH HO O H 1. NH 2 OH 2. Ac 2 O 3. 100 o C 4. NaOH, H 2 O C H HO H OH OH H CH 2 OH O H 1. NaCN, HCl 2. H 2 , Lindlar cat. 3. H 3 O + O OH OH OH OH CH 2 OH CH 3 OH H + HO This rxn occurs on the open form C OH OH H H OH OH H CH 2 OH H O H Br 2 , H 2 O C OH OH H H OH OH H CH 2 OH H O HO This rxn occurs on the cyclic form O H 3 CO OCH 3 OCH 3 OCH 3 H 3 CO This rxn occurs on the open form This rxn occurs on the open form This rxn occurs on the open form This rxn occurs on the cyclic form C OH H HO H OH OH H C H O HO O OH C H HO HO H OH H CH 2 OH H O H HO H OH OH H CH 2 OH OH H O H O OH OH OH CH 2 OH OCH 3
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WORK FOR HOMEWORK O HO OH OH OH OH O HO OH OH OH C H H HO HO H OH H CH 2 OH HO O H C H H HO HO H OH H CH 2 OH HO O H C OH H HO H H HO CH 2 OH O H CH 3 CH 2 OH H + HO O O O pyridine CH 3 OH H + 1. NaBH 4 2. H
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Problem_Set_10_Key - Problem Set 10: Chapter 25 1. Complete...

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